含溴水臭氧化过程中各溴类物质的生成和分布

Formation and distribution of bromine species during ozonation in filtered surface water containing bromide

摘要:

为寻求控制各溴类副产物生成的有效途径,研究了含溴水在臭氧氧化过程中,Br-质量浓度和臭氧投量综合作用对溴酸盐(BrO3-)和溴代三卤甲烷生成势(THMFP-Br)生成量的影响,以及臭氧投量和臭氧接触时间对THMFP-Br、BrO3-、总有机溴(TOBr)等溴类物质分布的影响.结果表明,不同Br-质量浓度下臭氧对THMFP-Br均有去除效果,低Br-质量浓度水中臭氧投量高时才有BrO3-生成.臭氧投量对TOBr中溴元素占初始Br-比例影响显著,而对THMFP-Br影响不大.臭氧化时间延长使BrO3-生成量增加,TOBr减少.

Abstract:

To investigate the effects of bromide concentration and ozone dosage on the formation of brominated trihalomethane formation potential (THMFP-Br) and BrO3-in ozonation,the effects of ozone dosage and reaction time on the distribution of bromide species were studied.The results show that THMFP-Br can be removed by ozone in water with different bromide concentrations.In low bromide concentration,BrO3-is formed only in high ozone dosage.Ozone dosage has great influence on the amount of total organic bromine (TOBr) on the percent conversion of Br-,but has no obvious effect on THMFP-Br.The generated BrO3-increases and the amount of TOBr decreases with the extended reaction time of ozonation.